408有機(jī)擔(dān)體是一種在氣相色譜(GC)中非常經(jīng)典的多孔聚合物固定相,由苯乙烯和二乙烯基苯共聚而成。它具有疏水性、耐高溫、極性弱等特點(diǎn),特別適用于分析揮發(fā)性有機(jī)物(VOCs)、永久氣體和低分子量極性化合物。
由于其性能與國(guó)際上知名的Porapak系列(如Porapak Q)?和Hayesep系列填料非常相似,因此在很多應(yīng)用中可以互換或作為替代品。
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特性描述主要優(yōu)點(diǎn)疏水性強(qiáng)(不懼水樣)、對(duì)極性化合物峰形好、耐高溫(通常可達(dá)250℃)、對(duì)CO?和輕烴分離效果好常用規(guī)格內(nèi)徑2-3 mm,長(zhǎng)度1-3米,80-100目,不銹鋼或玻璃材質(zhì)主要應(yīng)用永久氣體、CO?、C1-C3輕烴、揮發(fā)性有機(jī)物(VOCs)、醇類、醛類、水分等注意事項(xiàng)1.?老化:新柱或長(zhǎng)時(shí)間未使用的柱子需要在最高使用溫度下(低于250℃)通載氣老化數(shù)小時(shí),以去除殘留雜質(zhì)和水分。
2.?樣品:避免注入高沸點(diǎn)或不易揮發(fā)的物質(zhì),以免污染固定相,導(dǎo)致柱效下降。
3.?替代品可與Porapak Q、Hayesep Q/N等系列柱子互為替代,但具體方法可能需要微調(diào)。
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名稱:填充柱
型號(hào):408有機(jī)擔(dān)體
規(guī)格:3m*1/8,60-80目
zui高溫度:250°C
應(yīng)用:水、醇、醛、酮、腈類等極性或可極化化合物的分離
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應(yīng)用:
安捷倫490在線/便攜,4890,5890,6890,7820,7890,8860,8890
島津GC-14C,GC-2010,GC-2014,GC-2030
賽默飛1310,1300,1610,1600
瓦里安3800系列
布魯克PE580,590,680,690
磐諾A90,福立GC9790,華愛,天瑞,天美,GC7900,川儀,北分瑞利,東西電子,魯南瑞虹,捷島/科曉
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浩瀚色譜(山東)應(yīng)用技術(shù)開發(fā)有限公司,研制的《408有機(jī)擔(dān)體色譜柱應(yīng)用賽默飛1300》:應(yīng)用實(shí)例
408有機(jī)擔(dān)體色譜填料在以下分析中可能有用武之地:
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水、醇、醛、酮、腈類等極性或可極化化合物的分離。成功分離了丙烯氨氧化制丙烯腈工藝中的水、氫qing酸、乙醛、丙xi醛、丙酮、丙烯腈等多種組分。
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一些弱極性或非極性化合物的分離。
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可能用于氣體分析,特別是永jiu氣體和低分子量烴類的分離






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408 organic support is a very classic porous polymer stationary phase in gas chromatography (GC), which is copolymerized from styrene and divinylbenzene. It has the characteristics of hydrophobicity, high temperature resistance, and weak polarity, making it particularly suitable for analyzing volatile organic compounds (VOCs), permanent gases, and low molecular weight polar compounds.
Due to its performance being very similar to internationally renowned Porapak series (such as Porapak Q) and Hayesep series fillers, it can be interchangeable or used as a substitute in many applications.
Main advantages of characteristic description: strong hydrophobicity (not afraid of water samples), good peak shape for polar compounds, high temperature resistance (usually up to 250 ℃), good separation effect for CO ? and light hydrocarbons. Common specifications include inner diameter of 2-3 mm, length of 1-3 meters, 80-100 mesh. Stainless steel or glass materials are mainly used for permanent gases, CO ?, C1~3 light hydrocarbons, volatile organic compounds (VOCs), alcohols, aldehydes, moisture, etc. Precautions: 1. Aging: New columns or columns that have not been used for a long time need to be aged with gas for several hours at the highest operating temperature (below 250 ℃) to remove residual impurities and moisture.
2. Sample: Avoid injecting high boiling or non-volatile substances to prevent contamination of the stationary phase and reduce column efficiency.
3. Substitutes can be used to replace Porapak Q, Hayesep Q/N and other series of columns, but the specific method may need to be fine tuned.
Name: Filler Column
Model: 408 Organic Carrier
Specification: 3m * 1/8, 60-80 mesh
Zui high temperature: 250 ° C
Application: Separation of polar or polarizable compounds such as water, alcohols, aldehydes, ketones, nitriles, etc
Application:
Agilent 490 online/portable, 48905890689088608890
Shimadzu GC-14C, GC-2010, GC-2014, GC-2030
Thermo Fisher Scientific 1310130016101600
Varian 3800 Series
Brooke PE580590680690
Panno A90, Fuli GC9790, Huaai, Tianrui, Tianmei, GC7900, Chuanyi, Beifen Ruili, Dongxi Electronics, Lunan Ruihong, Jiedao/Kexiao
Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. has developed the "408 Organic Carrier Chromatography Column Application Thermo Fisher Scientific 1300": Application Example
408 organic support chromatography packing may be useful in the following analyses:
Separation of polar or polarizable compounds such as water, alcohols, aldehydes, ketones, nitriles, etc. Successfully separated various components such as water, hydrochloric acid, acetaldehyde, acetaldehyde, acetone, acrylonitrile, etc. in the process of producing acrylonitrile by ammoxidation of propylene.
Separation of some weakly polar or non-polar compounds.
May be used for gas analysis, especially for the separation of noble gases and low molecular weight hydrocarbons
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